A man was taken to Dubbo Hospital with head lacerations and leg pain after a crash near Dubbo on Tuesday afternoon.
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Emergency services were called to the Newell Highway at Purvis Lane about 1.15pm following reports a truck had rolled over and someone was trapped inside.
Paramedics treated a man in his 40s at the scene before he was conveyed to Dubbo Hospital, where he remains in a stable condition.
A Fire and Rescue NSW spokesperson said HAZMAT crews from Dubbo worked for several hours to contain and remove a 1300L diesel spill from the overturned truck, which had been carrying bales of wool.
Traffic had to be diverted around the site for several hours while a recovery operation took place.
An investigation is under way into the cause of the crash.